منابع مشابه
Nitrogen Quadrupole Coupling in the Microwave Ground State Spectra of Tertiary Butyl Isocyanide and Phenyl Isocyanide
Z. Naturforsch. 41 a, 1302-1306 (1986); received August 7, 1986 The microwave ground state spectra of tert.-butyl isocyanide, (CH3)3CNC, and phenyl isocyanide, C6H 5NC, have been measured by microwave Fourier transform spectroscopy in the region 5.0 to 8.0 GHz and analysed for nuclear quadrupole hyperfine splitting due to ‘*N. The nuclear quadrupole coupling constants are shown to be in accorda...
متن کاملTris(tert-butyl isocyanide-κC)carbonylnickel(0)
The title compound, [Ni(C(5)H(9)N)(3)(CO)], was prepared from Ni(CO)(4) and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent mol-ecules per asymmetric unit. The central Ni atom of each independent mol-ecule has a nearly perfect tetra-hedral coordination environment, comprising one carbon monoxide and three isocyanide ligands. The title compound is the fir...
متن کاملA Universal Isocyanide for Diverse Heterocycle Syntheses
Novel scaffolds are of uttermost importance for the discovery of functional material. Three different heterocyclic scaffolds easily accessible from isocyanoacetaldehyde dimethylacetal 1 by multicomponent reaction (MCR) are described. They can be efficiently synthesized by a Ugi tetrazole multicomponent reaction of 1. We discuss the synthesis, 3D structures, and other physicochemical properties.
متن کاملCrystal structure of p-toluenesulfonylmethyl isocyanide
The mol-ecule of the commercially available title compound, C9H9NO2S, has crystallographically imposed mirror symmetry, the mirror plane passing through the isocyanide group and the para-C atoms, the methyl C atom and the S atom of the methyl 4-tolyl sulfone moiety. In the crystal, C-H⋯O hydrogen-bond inter-actions link the mol-ecules into chains running parallel to the b axis.
متن کاملTa(CNDipp)6 : An Isocyanide Analogue of Hexacarbonyltantalum(0).
Hexakis(2,6-diisopropylphenylisocyanide)tantalum is the first isocyanide analogue of the highly unstable Ta(CO)6 and represents the only well-defined zerovalent tantalum complex to be prepared by conventional laboratory methods. Two prior examples of homoleptic Ta0 complexes are known, Ta(benzene)2 and Ta(dmpe)3 , dmpe=1,2-bis(dimethylphosphano)ethane, but these have only been accessed via liga...
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ژورنال
عنوان ژورنال: Green Chemistry
سال: 2020
ISSN: 1463-9262,1463-9270
DOI: 10.1039/d0gc02722g